You really should have a professional do it.
That said... The refrigerant pressure sensor/switch will not allow the compressor to turn on if there is not sufficient refrigerant (pressure) in the system. If the system is at vacuum and holding, you should be able to buy a can or two of refrigerant and a manifold gauge set, and refill it manually. Remember the system fill is in grams.
1. Hook the gauges up to the high and low sides of the a/c system. You want all the valves closed. The gauges should read vacuum on both. If not, you have a leak still.
2. Weigh the can. Prob need a kitchen scale. If you can have it sit on the scale while filling it that'd be great. If not, periodically weigh it (but do not disconnect it).
3. Connect the can to the manifold. This will be the center hose. Remember--keep the valve shut.
4. Start the car and turn the a/c on LO.
5. Open the center valve and then the low pressure side valve and start filling. You should start seeing the gauges start increasing from vacuum to some positive pressure.
6. Once you have filled enough refrigerant, the switch will allow the compressor to kick on. At this point you will see a radical difference in pressure between the two sides.
7. Continue filling until you have entered the correct weight of refrigerant. At that point, your low side should be 2.5-3.5 bar and high side should be around 15-20 bar or so. This is ambient temperature dependent too, so may vary. Feel/measure the vent temperatures.
8. Close the fill valve and then remove the manifold gauges from the car. Keep in mind when disconnect the can from the gauge set, a small amount in the hose will leak out.
9. Enjoy cold air conditioning!
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