I'm no expert on thermodynamics or air velocity, but I do believe that ceramic coating the INSIDE of a manifold would be counter-intuitive. Inside the manifold, you typically want your air velocities to be high (or higher than stock for performance purpose). From what I understand, this is achieve partially by smooth surfaces along the paths where air travels. The smoother the surface, the faster the air is capable of traveling (i.e. reduced resistence). This is why porting (increasing the size of intake and exhaust ports to increase air volume) and polishing (smoothing the ports/reducing any points of resistance in the intake and exhaust tracks) are CRUCIAL/popular options when deciding to increase air-flow in either your intake or exhaust manifolds, or cylinder heads.
Now, your theory on ceramic coating to increase exhaust temps to further increase exhaust velocity is theoretically good. However, the reason why ceramic coating the INSIDE is a bad idea, is because it doesn't create that smoother surface that we're looking for (not to mention that it'd be pretty hard to coat the inside of a manifold evenly). Thus, you'd be creating even more grooves within your manifold that will disrupt the flow of air. Though small these grooves might be, they wouldn't offer an improvement over going with a stock, unaltered manifold, IMO. While you might get some of the heating benefits of the coating, you'd be losing out of airflow.......But, ceramic coating the OUTSIDE is what you'd want to do. Then, if you'd got the time, money, or know-how....polishing and port the inside of the manifolds.
Bookmarks