are you thinking of powder coating your OEM calipers? You would definitely need to completely take apart the caliper and give them only the caliper core. Anything else would get fried, especially anything rubber. The piston could invariably seize too. Keep in mind, it's not only that things would melt, but as you know, when metal is heated at any temp, parts tend to expand. The piston, which is probably a harder metal than the caliper core may expand and split the core.
IMO, you really don't need to go to that extreme. Many guys on here either spray their calipers with 500 or 1200 degree engine paint that you can get from the auto parts store, or use the various caliper paint kits. Remember, you are only going to see some of the caliper through the wheel as well as a few glimpses of the carrier. You need not paint the entire thing.
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